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- The fresh dz2 and you can dx2-y2 orbitals do not have as the head get in touch with as the ligands kind of press prior otherwise slip by the such orbitals, therefore lowering the electron-electron repulsion as well as the time of your own orbital.
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In the systems of one’s smaller Planck constant ħ, the particles you to definitely move in step three size have possibly integer twist and you will follow Bose-Einstein statistics otherwise half of-integer twist and obey Fermi-Dirac statistics. As the bromo ligand are a failing career ligand , so it molecule is actually high twist. The new splitting out of tetrahedral complexes is actually myself contrary that of the brand new busting of your own octahedral buildings. Remember one to inside the octahedral buildings, the new dz2 and you may dx2-y2 orbitals features higher times versus dxz, dxy, and dyz orbitals. Within the tetrahedral buildings, the exact opposite takes place because the dxz, dxy, and you may dyz orbitals features higher times than the dz2 and dx2-y2 orbitals.
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